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derive the equation of crictical constant from vanderwaal's constants in short method |
vander Waal's equation for one mole of gas, ----------> (1)![]() At critical point T = Tc, P = Pc and V =Vc V = Vc V - Vc = 0 V3 - 3V2Vc + 3VVc2 - Vc3 = 0 This equation is identical with vander Waal's equation(ie cubic equation in V) Equating the both cubic equations' ![]() |
----------> (1)
