Call 1800-123-2003
what is the difference between commion ion effect and buffer solution |
Common ion effect In a solution of a weak electrolyte, the moleculer of the electrolyte are in equilibrium with its ions. For example a weak electrolyte AB is in equilibrium with A+ and B- in solution. The equilibrium is characterized by equilibrium constant, If the concentration of A+ or B- is increased, the equation would shift towards ldft, that is more AB is formed due to the combination of A+ and B-. The concentration of A+ and B- can be chaneged by adding a strong electrolyte having one ion is common with the electrolyte(AB) Definition A shift in the position of the equilibrium involving molecular form (AB) and ionic form (A+, B-) of an electrolyte, by adding a strong electrolyte having one ion common to it is called common-ion effect. Buffer solutions: A buffer is a solution that can maintain a nearly constant pH when diluted or when strong acids/ bases are added. A buffer solution consists of a mixture of a weak acid and its confugate base/ a weak base and its confugate acid. Example : CH3COOH and CH3COONa Any strong base that is added to the solution is neutralized by acetic acid. CH3COOH + OH- ? CH3COO- + H2O Any strong acid that is added to the solution is neutralized by acetate. CH3COO- + H+ ? CH3COOH The amount of strong acid or base that a buffer can neutralise is called buffer capacity. After neutralization, the equilibrium will be reestablished. In general, a buffer can be prepared by,
|