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what is the difference between commion ion effect and buffer solution

Common ion effect

In a solution of a weak electrolyte, the moleculer of the electrolyte are in equilibrium with its ions. For example a weak electrolyte AB is in equilibrium with A+ and B- in solution.
that is AB ?  A+ + B-

The equilibrium is characterized by equilibrium constant,

                         

If the concentration of A+ or B- is increased, the equation would shift towards ldft, that is more AB is formed due to the combination of A+ and B-. The concentration of A+ and B- can be chaneged by adding a strong electrolyte having one ion is common with the electrolyte(AB)

Definition

A shift in the position of the equilibrium involving molecular form (AB) and ionic form (A+, B-) of an electrolyte, by adding a strong electrolyte having one ion common to it is called common-ion effect.

Buffer solutions:

A buffer is a solution that can maintain a nearly constant pH when diluted or when strong acids/ bases are added. A buffer solution consists of a mixture of a weak acid and its confugate base/ a weak base and its confugate acid.

Example : CH3COOH and CH3COONa

Any strong base that is added to the solution is neutralized by acetic acid.

CH3COOH   +    OH-   ?  CH3COO-   +   H2O
         (aq)              (aq)                    (aq)          (aq)

Any strong acid that is added to the solution is neutralized by acetate.

CH3COO      +   H+   ?       CH3COOH
            (aq)            (aq)                      (aq)

The amount of strong acid or base that a buffer can neutralise is called buffer capacity. After neutralization, the equilibrium will be reestablished.

In general, a buffer can be prepared by,

  1. Mixing a weak acid and a salt of its confugate base in solution.
  2. Mixing of a weak acid and anough strong base to neutralize a portion of the weak acid.
  3. Mixing a weak base and enough strong acid to neutralise a portion of the weak base.


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