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Define electrolyte, electrode and electrolosis |
Electrode, electric conductor, usually metal, used as either of the two terminals of an electrically conducting medium; it conducts current into and out of the medium, which may be an electrolytic solution as in a storage battery, or a solid, gas, or vacuum. The electrode from which electrons emerge is called the cathode and is designated as negative; the electrode that receives electrons is called the anode and is designated as positive. In an electron tube, the anode is called the plate, and conducting elements that regulate the electron flow inside the tube are also called electrodes. Electrolyte, substance that conducts electric current as a result of a dissociation into positively and negatively charged particles called ions, which migrate toward and ordinarily are discharged at the negative and positive terminals (cathode and anode) of an electric circuit, respectively. The most familiar electrolytes are acids, bases, and salts, which ionize when dissolved in such solvents as water or alcohol. Many salts, such as sodium chloride, behave as electrolytes when melted in the absence of any solvent; and some, such as silver iodide, are electrolytes even in the solid state. Electrolysis, process by which electric current is passed through a substance to effect a chemical change. The chemical change is one in which the substance loses or gains an electron (oxidation or reduction). The process is carried out in an electrolytic cell, an apparatus consisting of positive and negative electrodes held apart and dipped into a solution containing positively and negatively charged ions. The substance to be transformed may form the electrode, may constitute the solution, or may be dissolved in the solution. Electric current (i.e., electrons) enters through the negatively charged electrode (cathode); positively charged components of the solution travel to this electrode, combine with the electrons, and are transformed to neutral elements or molecules. The negatively charged components of the solution travel to the other electrode (anode), give up their electrons, and are transformed into neutral elements or molecules. If the substance to be transformed is the electrode, the reaction is generally one in which the electrode dissolves by giving up electrons. Electrolysis is used extensively in metallurgical processes, such as in extraction (electro winning) or purification (electro refining) of metals from ores or compounds and in deposition of metals from solution (electroplating). Metallic sodium and chlorine gas are produced by the electrolysis of molten sodium chloride; electrolysis of an aqueous solution of sodium chloride yields sodium hydroxide and chlorine gas. Hydrogen and oxygen are produced by the electrolysis of water. |