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Types of redox reaction |
Redox (reduction-oxidation) reactions are those in which the oxidation states of the reactants change. This occurs because in such reactions, electrons are always transferred between species. Redox reactions take place through either a simple process, such as the burning of carbon in oxygen to yield carbon dioxide (CO2). Combination: Combination reactions "combine" elements to form a chemical compound. As usual, oxidation and reduction occur together. H2 + O2 → 2 H2O The sum of oxidation states in the reactants is equal to that in theproducts: 0 + 0 → (2)(+1) + (-2) In this equation, both H2
and O2 are the molecular forms of their respective elements and
therefore their oxidation states are 0. The product is H2O: the
oxidation state is -2 for oxygen and +1 for hydrogen. Decomposition reactions are the reverse of combination reactions, meaning they are the breakdown of a chemical compound into its component elements.Displacement:Displacement reactions, also known as replacement reactions, involve compounds and the "replacing" of elements. They occur as single and double replacement reactions. Cl2 + 2 NaBr → 2 NaCl + Br2 Calculation: 0 + [(+1) + (-1) = 0] In this equation, Cl is reduced and replaces Br, while Br is oxidized. General equation (double displacement): AB + CD → AD + CB A double replacement reaction is similar to a single replacement reaction, but involves "replacing" two elements in the reactants with two in the products. Equation: Fe2O3
+ 6 HCl → 2 FeCl3 + 3 H2O Combustion reactions always involve oxygen and an organic fuel. In the following image, we see methane combusting to release energy. Disproportionation: In some redox reactions, substances can be both oxidized and reduced. These are known as disproportionation reactions. One real-life example of such a process is the reaction of hydrogen. |