According
to the kinetic equation of pressure of a gas: |
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P
= r 1/3
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But
r = density of gas
r
= density of gas = mass of gas / volume of gas
r
= density of gas = mN / V
Putting the value of density
(r) |
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P
= 1/3
(mN / V )
P V=
1/3
(mN)
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But
PV = nRT
putting the value of PV, we get, |
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nRT=
1/3
(mN)
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Since
number of mole (n) = molecules/Avogadro's number
number of mole (n) = N/NA |
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Therefore,
|
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[N/NA]
R T= 1/3
(mN)
NA R T= 1/3
(m)
3 [NA R] T=
(m)
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But
NA R = Boltzman's constant (K), |
3
K T=
(m)
|
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Multiplying
both by 1/2 |
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(3/2)
K T=
(1/2) m
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(1/2)
m
= (3/2) K T
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But
(1/2) m
= average translational kinetic energy of gas molecules = (K.E)av
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(K.E)av
= (3/2) K T
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As
(3/2) K is a constant term,
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(K.E)av
= (constant) T
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