Without losing its concentration ZnCl2 solution cannot be kept in contact with
Au
Al
Pb
Ag
Standard electrode potentials are
Fe2+ / Fe, Eo = - 0.44 V
Fe3+ / Fe2+ , Eo = 0.77 V
Fe2+, Fe3+ and Fe block are kept together, then
Fe3+ increases
Fe3+ decreases
Fe2+/Fe3+ remains unchanged
Fe2+ decreases
Cu+ (aq) is unstable in solution and undergoes simultaneous oxidation and reduction according to the reaction
2 Cu+ (aq) Cu2+ (aq) + Cu (s)
Choose the correct Eo for above reaction if
- 0.38 V
+ 0.49 V
+ 0.38 V
- 0.19 V
The specific conductance of a 0.1 N KCl solution at 23o C is 0.012 ohm-1 cm-1. The resistance of cell containing the solution at the same temperature was found to be 55 ohm. The cell constant will be
0.142 cm-1
0.66 cm-1
0.918 cm-1
1.12 cm-1
An electrochemical cell is shown below
Pt, H2 (1 atm) |HCl (0.1 M)| CH3COOH(0.1 M)| H2 (1 atm), Pt. the emf of the cell will not be zero, because
emf depends on molarities of acids used
pH of 0.1 M HCl and 0.1 M CH3CHOOH is not same
The temperature is constant
Acids used in two compartments are different
Kohlrausch's law states that at
Finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.
Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte depending on the nature of the other ion of the electrolyte.
Infinite dilution, each ion makes definite contribution to conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.
Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.
EoFe2+/Fe = -0.441 V and EoFe2+/Fe2+= 0.771V, the standard emf of the reaction Fe +2Fe3+ →3Fe 2+ will be
0.111 V
0.330 V
1.653 V
1.212 V
The efficiency of a fuel cell is given by
ΔG / ΔS
ΔG / ΔH
ΔS / ΔG
ΔH / ΔG
A hypothetical electrochemical cell is shown below
A | A+ (xM) || B+ (yM) | B
The emf measured is + 0.20 V. The cell reaction is
A + B+ → A+ + B
A+ + B → A + B+
A+ + e- → A; B+ + e- → B
The cell reaction cannot be predicted
4.5 g of aluminium (at. mass 27 u) is deposited at cathode from Al3+ solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from H+ ions in solution by the same quantity of electric charge will be
44.8 L
22.4 L
11.2 L
5.6 L