Percentage composition of an organic compound as determined by analysis was carbon 14.5, hydrogen 1.8, chlorine 64.46, and oxygen 19.24. The empirical formula of the compound is
CH3Cl3O2
CH2Cl2O
CH3Cl2O
C2H3Cl3O2
When a solid is heated with fusion mixture of sodium carbonate and potassium nitrate, a yellow precipitate is obtained. It indicates the presence of
Na
Cl
S
P
When 0.25g of an organic compound is heated with HNO3 and AgNO3 in a Carius tube, it gives 0.35 g of silver chlodide. The percentage of chlorine in the compound is
34.6%
36.6%
46.5%
56.9%
In an experiment, 0.26g of an organic compound, in a quantitative analysis, yielded 0.35 g of barium sulphate. The percentage of sulphur in the substance is
14.5
16.5
18.5
19.5
The best method for the separation of naphthalene and benzoic acid from their mixture is
Distillation
Sublimation
Crystallisation
Chromatography
Empirical formula of a compound is CH2Br. If its vapour density is 93.5, then the molecular formula of the compound is
CH4Br2
C2H4Br
C4H2Br2
C2H4Br2
On ignition, 0.3585 g of platinum, 0.98 g of the platinichloride of diacid base left. The molecular weight of the base is
70
90
109
123
In the detection of sulphur in an organic compound, sodium nitropruside solution is added to the Lassaigne’s test solution. A purple color is obtained due to the formation of
F(CNS)3
Na3Fe(CN)6
Na3[Fe(CN)5NS]
Na3[Fe(CN)5NOSNa]
The presence of halogen, in an organic compound, is detected by
Millon’s test
Beilstein’s test
Iodoform test
Silver nitrate test
On combustion, 0.2 g of an organic compound containing carbon, hydrogen and oxygen yields 0.147 g carbon dioxide and 0.12 g water. The percentage of carbon, hydrogen and oxygen respectively in the compound are
20, 6.7 and 73.3
22.5, 8.7 and 68.8
18.2, 9.5 and 72.3
28.6, 12.8 and 58.8