An organic substance on analysis was found to contain 10.06 percent carbon, 0.84 percent hydrogen and 89.10 percent chlorine. Its empirical formula is
C2H2Cl2
C2H5Cl
CHCl3
CHCl4
The most suitable method for the separation of a 1:1 mixture of ortho- and para- nitrophenols is
Filtration
Sublimation
Crystallisation
Steam distillation
In an experiment, 0.1877g of an organic compound when analyzed by the Dumas method yielded 31.7 ml of moist nitrogen measured at 140C and 758 mm mercury pressure. The percentage of nitrogen in the compound is (Aqueous tension at 140C = 12 mm)
19.7
22.3
24.3
25.6
Which of the following has molecular weight of 92 ?
Toluene
Benzene
Methylene
Propane
In the detection of sulphur in an organic compound, sodium nitropruside solution is added to the Lassaigne’s test solution. A purple color is obtained due to the formation of
F(CNS)3
Na3Fe(CN)6
Na3[Fe(CN)5NS]
Na3[Fe(CN)5NOSNa]
An organic compound containing C, H and N gave the following analysis: C = 40%, H = 13.33% and N = 46.67%. The empirical formula of the compound would be
CHN
CH4N
C2H2N
C2H7N
Concentrated nitric acid is added to Lassaigne’s extract in the detection of halogen to
Help in the precipitation of AgCl
Decomposes Na2S and NaCN, if formed
Increase the solubility product of AgCl
Increase the concentration of nitrate ions
The two impure substances, which do not have large differences in their solubilities, are purified by
Distillation
Concentration
Fractional crystallisation
If a sample of organic substance is heated strongly with soda-lime in a test tube, then ammonia is evolved. It indicates the presence of
Nitrogen
Sulphur
Oxygen
Carbon
The percentage of N2 in urea is
18.1
28.3
46.7
85.6