Which of the following molecules acts as a Lewis acid ?
(CH3)3B
(CH3)2O
(CH3)3P
(CH3)3N
A weak acid HA, has a Ka of 1.00 ×10-5. If 0.100 mole of this acid is dissolved in one litre of water, the percentage of acid dissociated at equilibrium is closest to
99.0%
1.00 %
99.9%
0.100%
The solubility of a saturated solution of calcium fluoride is 2×10-4 mol / L . Its solubility product is
12×10-2
14×10-4
22×10-11
32×10-12
Which of the following is most soluble ?
Bi2S3(KSP=1×10-70)
MnS(KSP=7×10-16)
CuS(KSP=8×10-37)
Ag2S(KSP=6×10-51)
The strongest conjugate base is
NO3-
Cl-
SO4 2-
CH3COO-
The conjugate acid of NH2- is
N2H4
NH4 +
NH2 OH
NH3
H2S gas when passed through a solution of cations containing HCl precipitates the cations of second group in qualitative analysis but not those belonging to the fourth group. It is because
Presence of HCl decreases the sulphide ion concentration.
Presence of HCl increases the sulphide ion concentration.
Solubility product of group 2nd sulphides is more than that of group iv sulphides
Sulphides of group iv cations are unstable in HCl
The solubility product of CuS ,CdS and HgS are 10-31 , 10-44 , 10-54 , respectively.The solubility of these sulphides are in the order .
CdS > HgS > CuS
HgS > CdS > CuS
CdS > CuS > HgS
CuS > CdS >HgS
The hydride ion H- is strong base than its hydroxide ion OH-. Which of the following reactions will occur if sodium hydride (NaH) is dissolved in water ?
2H-(aq) + H2O(l)→H2O+H2 +2e-
H-(aq) + H2O(l)→OH-+H2
H - + H2O(l) → no reaction
None of the above
A Physician wishes to prepare a buffer solution at pH =3.58 that efficiently resist changes in pH yet contains only small concentration of the buffering agents. Which one of the following weak acid together with its sodium salt would be best to use ?
m-chlorobenzoic acid (pKa=3.98)
P-Chlorocinnamic acid(pKa = 4.41)
2,5 -dihydroxy benzoic acid (pKa=2.97)
Acetoacetic acid(pKa=3.58)