On the basis of the following Eovalues, the strongest oxidising agent is.
[Fe(CN)6]4-
Fe2+
Fe3+
[Fe(CN)6]3
Standard free energies of formation (in KJ/mol) at 298 K are -237.2, -394.4 and -8.2 for H2O(l) CO2(g) and pentane (g), respectively. The value of Eocell for the pentane-oxygen fuel cell is.
1.968 V
2.0968 V
1.0968 V
0.0968 V
In electrolysis of NaCI when Pt electrode is taken then H2 is liberated at cathode while with Hg cathode it forms sodium amalgam because.
Hg is more inert than Pt.
More voltage is required to reduce H+ at Hg than at Pt.
Na is dissolved in Hg while it does not dissolved in Pt.
Concentration of H+ ions is larger when Pt electrode is taken.
4.5 g of aluminium (at.mass 27 u) is deposited at cathode from AI3+ solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from H+ ions in solution by the same quantity of electric charge will be
44.8 L
22.4 L
11.2 L
5.6 L
Which one of the following pairs of substances on reaction will not evolve H2 gas.
Iron and H2SO4 (aqueous).
Iron and steam.
Copper and HCI (aqueous).
Sodium and ethyl alcohol.
Standard reduction potentials at 25oC of Li+/Li,Ba2+/Ba,Na+/Na and Mg2+/Mg are -3.05,-2.90,2.71 and -2.37 volt respectively. Which one of the following is the strongest oxidising agent ?
Mg2+
Ba2+
Na+
Li+
For the cell reaction,
In(C1)
In(C2/C1)
In(C2)
In (C1+C2)
Standard electrode potentials are
Fe3+ increases
Fe3+ decreases
remains unchanged
Fe2+ decreases
Eo for the cell, Zn [Zn2+ (aq)] [Cu2+(aq)] Cu is 1.10 V at 25oC. The equilibrium constant for the reaction,
10-37
10-28
10-18
10-17
AI2o3 is reduced by electrolysis at low potentials and high currents. If 4.0 x 104 A of current is passed through molten AI2O3for 6 h, what mass of aluminium is produced ? (Assume 100% current efficiency, at mass of AI = 27 g mol-1)
9.0 x 103g
8.1 x 104g
2.4 x 105g
1.3 x 104g