Aniline is reacted with bromine water and the resulting product is treated with an aqueous solution of sodium nitrite in presence of dilute hydrochloric acid. The compound so formed is converted into a tetrafluoroborate which is subsequently heated. The final product is
1,3,5-tribromobenzene
p-bromofluorobenzene
p-bromoaniline
2,4,6-tribromofluorobenzene
Which of the following is more basic than aniline ?
Diphenylamine
Triphenylamine
p-nitroaniline
Benzylamine
Aniline is an activated system for electrophilic substitution. The compound formed on heating aniline with acetic anhydride is
Intermediates formed during reaction of
with Br2 and KOH atr
RCONHBr and RNCO
RNHCOBr and RNCO
RNHBr and RCONHBr
RCONBr2
Phenyl isocyanides are prepared from which of the following reaction ?
Rosenmund's reaction
Carbylamine reaction
Reimer-Tiemann reaction
Wurtz reaction
Amides can be converted into amines by a reaction named after
Perkin
Claisen
Hofmann
Kekule
What is the decreasing order of basicity of 1o , 2o and 3o ethyl amines and ammonia ?
NH3 > C2H5NH2 > (C2H5)2 NH > (C2H5)3N
(C2H5)3N > (C2H5)2 NH > C2H5 NH2 > NH3
(C2H5)3NH > C2H5 NH2 > (C2H5 )3 N > NH3
(C2H5)2NH > (C2H5)3 N > C2H5 NH2 > NH3
Which one of the following on reduction with LiAIH4 yields a secondary amine ?
Methyl isocyanide
Acetamide
Methyl cyanide
Nitroethane
A reagent suitable for the determination of N-terminal residue of a peptide is
p-toluene sulphonyl chloride
2,4-dinitrophenyl hydrazine
carboxypeptidase
2,4-dinitro fluorobenzene
Acetamide and ethyl amine can be distinguished by reacting with
aqueous HCI and heat
aqueous NaOH and heat
acidified KMnO4
bromine water