Phenyl isocyanides are prepared from which of the following reaction ?
Rosenmund's reaction
Carbylamine reaction
Reimer-Tiemann reaction
Wurtz reaction
Intermediates formed during reaction of
with Br2 and KOH atr
RCONHBr and RNCO
RNHCOBr and RNCO
RNHBr and RCONHBr
RCONBr2
An organic compound A on reduction with chloroform and potassium hydroxide forms C. The compound C on catalytic reduction gives N-methylaniline. The compound A is
nitrobenzene
nitromethane
methylamine
aniline
Consider the following sequence of reactions
Compound
The compound [A] is
CH3CH2CN
CH3NO2
CH3NC
CH3CN
Which one of the following on reduction with LiAIH4 yields a secondary amine ?
Methyl isocyanide
Acetamide
Methyl cyanide
Nitroethane
What is the decreasing order of basicity of 1o , 2o and 3o ethyl amines and ammonia ?
NH3 > C2H5NH2 > (C2H5)2 NH > (C2H5)3N
(C2H5)3N > (C2H5)2 NH > C2H5 NH2 > NH3
(C2H5)3NH > C2H5 NH2 > (C2H5 )3 N > NH3
(C2H5)2NH > (C2H5)3 N > C2H5 NH2 > NH3
Aniline in a set of reactions yielded a product D.
The structure of the product D would be
C6H5CH2NH2
C6H5NHCH2CH3
C6H5NHOH
C6H5CH2OH
Indicate which nitrogen compound amongst the following would undergo Hofmann reaction ?
RCONHCH3
RCOONH4
RCONH2
RCONHOH
Mark the correct statement.
Methyl amine is slightly acidic
Methyl amine is less basic than ammonia
Methyl amine is a stronger base than NH3
Methyl amine forms salts with alkalies
The final product C, obtained in this reaction
would be