The number of geometrical isomers for [Pt(NH3)2]Cl2 is
3
4
1
2
Shape of Fe(CO)5 is
Octahedral
Square planar
Trigonal bipyramidal
Square pyramidal
In the separation of Cu2+ and Cd2+ of IInd group in qualitative analysis of cations, tetrammine copper (II) sulphate and tetrammine cadmium (II) sulphate react with KCN to form the corresponding cyano complexes, which one of the following pairs of the complexes and their relative stability enables the separation of Cu2+ and Cd2+?
K3[Cu(CN)4] : less stable and
K2[Cd(CN)4] : more stable
K3[Cu(CN)4] : more stable and
K2[Cd(CN)4] : less stable
K2[Cu(CN)4] : less stable and
K2[Cu(CN)4] : more stable and
The coordination number and oxidation state of Cr in K3[Cr(C2O4)3] are respectively
3 and +3
3 and 0
6 and +3
4 and +2
Which of the following ligands is expected to be bidentate?
CH3NH2
CH3C ≡ N
Br
C2O2-4
A coordination complex compound of cobalt has the molecular formula containing five ammonia molecules, one nitro group and two chlorine atoms for one cobalt atom. One mole of this compound produces three mole ions in an aqueous solution. On reacting this solution with excess of AgNO3 solution, we get two moles of AgCl precipitate. The ionic formula for this complex would be
[Co(NH3)5(NO2)]Cl2
[Co(NH3)5Cl] [(NO2)]Cl2
[Co(NH3)4(NO2)]Cl] [NH3)Cl]
[Co(NH3)5] [(NO2)2Cl2]
IUPAC name of [Pt(NH3)3 (Br) (NO2) Cl] Cl is
Triamminebromochloronitroplatinum (IV) chloride
Triamminebromonitrochloplatinum (IV) chloride
Triamminechlorobromonitroplatinum (IV) chloride
Triamminenitrochlorobromoplatinum (IV) chloride
Which of the following organometallic compounds is σ and π bonded?
[Fe(η5 - C5H5)2]
K[PtCl3 (η2 - C2H4)]
[Co(CO)5 NH]3]2+
Fe(CH3)3
The total number of possible isomers for the complex compound [CuII (NH3)4] [PtIICl4] are
5
6
Atomic number of Cr and Fe are respectively 24 and 26, which of the following is paramagnetic with the spin of electron?
[Cr(CO)6]
[Fe(CO)5]
[Fe(CN)6]4-
[Cr(NH3)6]3+
