Self condensation of two moles of ethyl acetate in presence of sodium ethoxide yields
ethyl butyrate
acetoacetic ester
methyl acetoacetate
ethyl propionate
The relative reactivities of acyl compounds towards nucleophilic substitution are in the order of
acyl chloride > acid anhydride > ester > amide
ester > acyl chloride > amide > acid anhydride
acid anhydride > amide > ester > acyl chloride
acyl chloride > ester > acid anhydride > amide
Which one of the following esters cannot undergo Claisen self-condensation ?
CH3CH2CH2CH2COOC2H5
C6H5COOC2H5
C6H5CH2COOC2H5
C6H11CH2COOC2H5
Benzoic acid may be converted into ethyl benzoate by reaction with
sodium ethoxide
ethyl chloride
dry HCI, C2H5OH
ethanol
An ester (A) with molecular formula C9H10O2 was treated with excess of CH3MgBr and the complex so formed was treated with H2SO4 to give an olefin (B). Ozonolysis of (B) gave a ketone with molecular formula C8H8O which shows positive iodoform test. The structure of (A) is
C6H5COOC6H5
H3CCOCH2COC6H5
p-H3CO-C6H4-COCH3
Propionic acid with Br2 - P yields a dibromo product. Its structure would be
CH2 Br-CHBr-COOH
CH2Br-CH-COBr
Schotten-Baumann reaction is a reaction of phenols with
benzoyl chloride and NaOH
acetyl chloride and NaOH
salicyclic acid and conc H2SO4
acetyl chloride and conc H2SO4
Which one of the following orders of acidic strength is correct ?
RCOOH > HOH > HC CH > ROH
RCOOH > HC CH > HOH > ROH
RCOOH > ROH > HOH > HC CH
RCOOH > HOH > ROH > HC CH
Among acetic acid, phenol and n-hexanol, which one of the following compound will react with NaHCO3 solution to give sodium salt and CO2 ?
Acetic acid
n-hexanol
Acetic acid and Phenol
Phenol
Formic acid is obtained when
calcium acetate is heated with conc H2SO4
calcium formate is heated with calcium acetate
glycerol is heated with oxalic acid at 373 K
acetaldehyde is oxidised with K2Cr2O7 and H2SO4