In a first order reaction A → B, if k is rate constant and initial concentration of the reactant A is 0.5 M, then the half-life is
A substance 'A' decomposes by a first order reaction starting initially with [A] = 2.00m and after 200 min, [A] becomes 0.15 m. For this reaction t1/2 is
53.50 min
50.4 min
48.45 min
46.45 min
The rate constants k1 and k2 for two different reaction are 1016.e-2000/T and 1015.e-1000/T, respectively. The temperature at which k1 = k2 is
1000 K
2000 K
The temperature dependance of rate constant (k) of a chemical reaction is written in terms of Arrhenius equation, k = Ae-E*/RT. Activation energy (E*) of the reaction can be calculated by plotting
log k vs 1/T
k vs T
For a first order reaction A → B, the reaction rate at reactant concentration of 0.01 M is found to be 2.0 × 10-5 mol L-1s-1. The half-life period of the reaction is
220 s
30 s
300 s
347 s
If 60% of a first order reaction was completed in 60 min, 50% of the same reaction would be completed in approximately
(log 4 = 0.60, log 5 = 0.69)
50 min
45 min
60 min
40 min
In gaseous reactions,the units of the rate equation will be ____________
Mol L-1
mol s-1
atm L-1
atm s-1
The reaction A → B follows first order kinetics. The time taken for 0.8 mole of A to produce 0.6 mole of B is 1 h. What is the time taken for the conversion of 0.9 mole of A to 0.675 mole of B?
0.25 h
2 h
1 h
0.5 h
For a first-order reaction, the half-life period is independent of
Initial concentration
Cube root of initial concentration
First power of final concentration
Square root of final concentration